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氧化镁改性生物炭的制备及其对阿魏酸的吸附作用
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唐婷范(1988-),女,博士,高级实验师,研究方向:制糖科学与工程;E-mail:tangtingfan@163.com 通讯作者:程昊(1980-),男,硕士,副研究员,研究方向:制糖科学与工程及应用化学;E-mail:iamchenghao@126.com

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广西自然科学基金重点项目(2019GXNSFDA245025);广西自然科学基金联合专项项目(2025GXNSFHA069196);广西自然科学基金面上项目(2022GXNSFAA035490);广西糖资源绿色加工重点实验室主任基金(GXTZYZR202401);广西研究生教育创新计划项目(YCSW2024511)


Preparation of Magnesium Oxide-modified Biochar and Its Adsorption of Ferulic Acid
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    摘要:

    该文以甘蔗渣为原料,通过优化煅烧条件制得吸附性能较好的生物炭,并引入镁盐制备氧化镁改性生物炭。 采用电子扫描电镜(Scanning Electron Microscope, SEM)、能谱仪(Energy Dispersive Spectrometer, EDS)、X射线衍射(X-ray Diffraction, XRD)和红外光谱(Infrared Spectroscopy, FT-IR)和比表面积和空隙度分析仪(Specific Surface Area and Porosity Analyzer, BET)表征。以对阿魏酸蔗糖溶液的吸附率为评价指标,探讨溶液pH值、吸附温度、吸附时间、吸附剂用量四个单因素最佳吸附条件。采用吸附动力学模型和热力学模型实验对数据进行拟合,探究其吸附行为。结果表明:在炭化温度600 ℃、炭化时间2 h下制得的生物炭吸附性能最佳;通过SEM、EDS、XRD、FT-IR和BET可知生物炭表面成功负载镁元素且孔结构发生了较大的变化,比表面积和空隙率大,吸附能力强;单因素实验测得的最佳条件为pH值为5.5、温度75 ℃、搅拌时间120 min、吸附剂用量150.00 mg;改性后生物炭对阿魏酸蔗糖溶液的吸附率为42.01%,相较于未改性生物炭29.01%及大孔树脂22.09%的吸附率有较大提升且吸附行为以多分子层的化学吸附为主。由此可见,氧化镁改性生物炭作为清净剂在糖汁澄清工艺中具有一定的应用前景。

    Abstract:

    This study used bagasse as the raw material to produce biochar with high adsorption capacity by optimizing calcination conditions and introduced magnesium salt to prepare magnesium oxide-modified biochar. The prepared biochar was characterized using Scanning Electron Microscopy (SEM), Energy Dispersive Spectrometry (EDS), X-ray Diffraction (XRD), Infrared Spectroscopy (FT-IR), and Specific Surface area and Porosity Analysis (BET). The adsorption rate on ferulic acid sucrose solution was used as the evaluation index to optimize four single factors: solution pH, adsorption temperature, adsorption time, and adsorbent dosage. Adsorption kinetics and thermodynamic models were applied to fit the experimental data and investigate adsorption behavior. The results showed that biochar produced at a carbonization temperature of 600 ℃ and a carbonization time of 2 h exhibited the best adsorption performance. SEM; EDS, XRD, FT-IR, and BET analyses confirmed successful magnesium loading and porosity, leading to enhanced adsorption capacity. The optimal conditions determined by single-factor experiments were pH 5.5, temperature 75 ℃, stirring time 120 min, and adsorbent dosage 150.00 mg. Under these conditions, the adsorption rate of modified biochar on ferulic acid sucrose solution reached 42.01%, markedly higher than that of unmodified biochar (29.01%) and macroporous resin (22.09%). Furthermore, the adsorption behavior was governed by multimolecular-layer chemical absorption. These findings suggest that magnesium oxide-modified biochar is a promising clarifying agent for sugar juice clarification.

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唐婷范,陈廷莎,韦竑志,李琦,李雪松,陈金足,何美妮,李利军,程昊.氧化镁改性生物炭的制备及其对阿魏酸的吸附作用[J].现代食品科技,2025,41(11):231-241.

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  • 收稿日期:2024-07-30
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  • 在线发布日期: 2025-12-05
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